"The invention relates to a low-pressure mercury vapour
discharge lamp having a vacuum-tight radiation-permeable
envelope provided with a luminescent layer, a gas filling
comprising mercury and a rare gas, and means for
maintaining a column discharge in the gas filling, the
power consumed by the column being at least 500 W/m2
surface area of the luminescent layer.
Low-pressure mercury vapour discharge lamps are
radiation sources which are used on a very large scale both
for general illumination and for special purposes (for
example, activating photochemical processes), because they
convert the electric power supplied very efficiently into
radiation. In general these lamps consist of a tubular
envelop which may be straight or curved, for example in the
form of a circle or U-shaped. This envelope contains a gas
mixture comprising mercury and one or more rare gases in
which a column discharge is produced. This column
discharge is maintained by supplying electric energy to the
gas mixture, usually through two electrodes. Mainly
ultra-violet radiation is produced in the discharge, a
comparatively small part of which radiation has wavelengths
of approximately 185 nm, the greatest part of the radiation
having wavelengths of approximately 254 nm. This
ultra-violet radiation is converted by means of a luminescent
layer located on the inner wall of the lamp envelope, into
radiation having a longer wavelength and a spectral
distribution, depending on the luminescent material used,
in the near ultra-violet or in the visible part of the
spectrum.
One of the commonest types of low-pressure mercury
vapour discharge lamp is the so-called 40 W/T12-lamp
consisting of a straight tube which has a length of
approximately 1.20 (meters) and an internal diameter of
approximately 37 mm, and consuming a power of approximately
40 W. In general this lamp is operated with a lamp current
of approximately 400 mA and an electric field strength in
the column of approximately 80 V/m. The temperature of the
coldest spot of the envelope of such a lamp which is
free-burning in air is, in these circumstances approximately
40 degrees, at which temperature there is a mercury vapour
pressure of approximately 6x10-3 torr in the lamp. It
appeared that these circumstances are substantially optimal
as regards the production of ultra-violet radiation. Other
frequently occurring lamp types have in operation lamp
current, electric field and mercury vapour pressure values
which correspond to the above-mentioned values or do not
deviate much therefrom. The wall load of these lamps, that
is to say the power input of the column per surface unit of
the luminescent layer, has a value of approximately 300
W/m2 in these lamps.
Low-pressure mercury vapour discharge lamps have
already been made, wherein a considerably higher wall
load, namely 500 W/m2 is applied, so that the electric
power input per volume unit of the lamp becomes
considerably greater. This was done in the first place
with the object of obtaining small and compact lamps.
German Offenlegungsschrift 2,109,898, for example,
discloses small lamps having wall loads up to approximately
2500 W/m2. The electric field strength in these lamps is
higher than in the normal lamps and has, for example, a
value of the order of 600V/m. In the second place, the use
of high current densities (from 0.5 to 25 A/cm2) enabled
the production of lamps whose wall is loaded very highly.
These lamps are, for example, disclosed in United States
Patent Specifications 3,778,662 and 3,679,928. Wall loads
of the order of 25,000 W/m2 may occur in these lamps.
A great drawback of the prior art lamps with a
relatively high wall load is that the efficiency of the
lamp, that is to say the radiant flux or luminous flux of
the useful radiation emitted by the luminescent layer (the
output of useful radiation per unit of electric power
applied to the lamp) appears to have a low value. In
particular this efficiency is considerably lower than that
of the normal lamp (for example the 40 W/T12-lamp). This
drawback is especially felt with the compact lamps and is
one of the reasons that this lamp type, which might offer
great advantages for practical applications, for example as
a substitute for normal incandescent lamps, has as yet not
been introduced. The reason why it appeared to be
impossible to produce lamps having a high power input per
unit volume and with an efficiency comparable to that of
the normal lamps was not understood. Also known insights
as regards the optimum mercury vapour pressure (which
appears to be higher for lamps which are loaded to a
greater extent, for example to 0.75 Torr at a temperature
of the coldest spot of the lamp of 120 degrees C) and means for
controlling the mercury vapour pressure (amalgams etc) did
not lead to the desired result. It has, therefore, been
considered that producing a compact lamp, for example by
reducing the diameter whilst maintaining the electric power
supplied must inevitably be accompanied by loss in
efficiency.
The invention has for its object to provide low-pressure
mercury vapour discharge lamps which in operation
has (have) a high density of the consumed power and a high
radiation efficiency, so that on the one hand compact lamps
with an efficiency substantially equal to that of the
normal low-pressure mercury vapour discharge lamps and, on
the other hand, lamps having high current densities with an
improved radiation efficiency become available.
The invention provides a low-pressure mercury vapour
discharge lamp having a vacuum-tight radiation-permeable
envelope bearing a luminescent layer and containing a gas
filling comprising mercury and a rare gas, and means for
maintaining a column discharge in the gas filling, the
power consumed during operation of the lamp by the column
discharge being at least 500 W/m2 of the surface area
of the luminescent layer, wherein the luminescent layer
comprises a luminescent material which has the property of
having at 254 nm excitation a luminous flux, which after
the material has been subjected for 15 minutes to
ultra-violet radiation consisting substantially of the
wavelengths 185 and 254 nm, having a radiating density
between 150 and 500 W/m2 and having a ratio of 185 nm power
to 254 nm power between 0.20 and 0.40, is not more than 5%
lower than the initial luminous flux of the material at 254
nm excitation and measured in identical circumstances, and
wherein the combination of cations (as hereinafter defined)
in the luminescent material has an electronegativity of not
more than 1.4.
During the investigations which led to the invention,
it was found that an efficient conversion of the electric
power into ultra-violet radiation is possible in a highly
loaded lamp. It was surprisingly found that the efficiency
of this conversion can be substantially equal to that of
the normal 40W/T12 lamp. It was found to be a prerequisite
that the electron temperature in the highly loaded lamp
assumes a value which is not lower, and is, preferably
higher than that in the normal lamp. Various measures are
possible to achieve this. Starting, for example, from the
normal lamp, the required high electron temperature is
maintained if the discharge tube has a smaller diameter,
while the electric power supplied to the lamp is kept
substantially constant. Compared to the normal lamps, the
electric field strength is then higher, the lamp current is
lower and the wall load is higher than in the normal lamps.
Experiments showed that said high efficiency of the
conversion into ultra-violet radiation can also be obtained
with very low diameters of the discharge tube (from one to
a few mm). Another measure which makes it possible to
maintain a high electron temperature is to reduce the rare
gas pressure in the lamp whilst increasing the supplied
electric power. Compared to the normal lamps the lamp
current is then considerably greater and the electric field
strength is substantially the same or is somewhat lower.
The wall load in these lamps is of course higher.
It was furthermore found that with an efficient
production of ultra-violet radiation in highly loaded
lamps, there is not only a high ultra-violet radiation
density at the wall but also the share of the radiation
having a wavelength of 185 nm is relatively higher than in
normal lamps. This unexpectedly high ratio between the 185
nm radiation and the 254 nm radiation combined with the
increased density of the total ultra-violet radiation
produced results in the 185 nm-load of the wall of such
lamps being considerably higher than in normal lamps.
The invention is based on the recognition that
failure of the prior art lamps with high wall load is not
due to a low efficiency of the conversion into ultra-violet
radiation, as has been generally assumed so far, but is due
to the luminescent materials used. The invention provides
suitable luminescent materials as a measure for obtaining
efficient, highly loaded lamps. Consequently, the present
invention opens the way to an entirely new lamp type,
namely the compact low-pressure mercury vapour discharge
lamp which can replace the normal incandescent lamp which
is used in very great numbers. As the efficiency of the
low-pressure mercury vapour discharge lamp is approximately
5 times greater than that of the incandescent lamp, a very
considerable saving in energy is possible. In a lamp
according to the invention a luminescent material is used
which is, on the one hand, highly resistant against 185 nm
radiation, that is to say it has only a very slight
decrease in the luminous flux (on excitation by 254 nm
radiation) owing to irradiation by 185 nm rays and which,
on the other hand, has a high mercury resistance.
It is known that subjecting a luminescent material to
185 nm radiation has in general even after a very short
period of time a detrimental effect on the luminous flux of
the luminescent material. As a measure of the resistance
to 185 nm radiation the so-called short term decrease is
used, which in this description is understood to mean the
decrease (in %) in the luminous flux of the material, when
excited by 254 nm radiation) (sic) as the result of an
irradiation for fifteen minutes by radiation having wave
lengths of mainly 185 nm and 254 nm with a radiation
density between 150 and 500 W/m2 and with a ratio of 185 nm
power to 254 nm- power between 0.20 and 0.40. An
arrangement for determining the short term decrease as well
as the value of this decrease for some luminescent
materials is known from "Illuminating Engineering" 59
(1964), pages 59-66. Such an arrangement will be described
in greater detail below. Owing to the high density of 185
nm radiation, high requirements are imposed in lamps
according to the invention on the short term decrease of
the luminescent material. This decrease shall not be more
than 5%. It has been found that for a higher value of this
decrease, lamps are obtained which furnish an unacceptably
low luminous flux after having burned for the few minutes
which are required for obtaining a steadily burning lamp;
in practice the short term decrease has already taken place
when the luminous flux of the lamp is measured at 0 hour.
In a lamp according to the invention the luminescent
material must not only satisfy the requirement as regards
the short term decrease but also the requirement for a
higher degree of mercury resistance. It has, namely, been
found that the luminous layer in highly loaded lamps is
exposed to a much greater number of collisions with excited
mercury atoms and mercury ions than is the case in normal
lamps. The highly energetic mercury atoms and ions can be
absorbed at the surface of the luminescent layer and/or
react with the luminescent material. Consequently a
darkening of the luminescent layer occurs which
considerably reduces the luminous flux of the lamp. A
measure of the mercury resistance of a luminescent material
is found in the electro-negativity (e.n.) of the cations of
the luminescent material. In this description and the
claims, cations is defined to mean the metals from the
series 1A, 1B, 2A, 2B and 3B of the periodic system of
elements as specified in "Handbook of Chemistry and
Physics", Cleveland (Ohio). The further elements are here
considered as anions or anion-forming elements. The values
of the electronegativity (e.n.) of the elements are given
in L. Pauling "The Nature of the Chemical Bond", New York
(1945). If the elements are arranged in a series on the
basis of an increasing value of the e.n. the so-called
electromotive series of the elements is obtained. In
principle a certain element can displace all elements from
this series having the same or a higher value for the e.n.
from a compound. It is now clear that mercury (which has
an electronegativity of 1.9) will attack luminescent
materials whose cation has e.n.>- 1.9 (these cations are
equally noble or nobler than mercury). It was (has) now
been found that the cation of a luminescent material
suitable for lamps according to the invention must have a
relatively low e.n., namely not more than 1.4. This can be
explained from the fact that the mercury in the discharge
plasma is richer in energy than neutral mercury and from
the fact that the number of times the mercury collides with
the luminescent layer is high. It was found, for example,
that a luminescent material containing zinc (e.n. = 1.6) as
a cation, which in normal lamps shows some mercury attack
only after a relatively long operating period can
definitely not be used in highly-loaded lamps because the
luminescent layer is already markedly darkened after the
lamp has burnt for a period of from some minutes to some
hours. If a luminescent material contains several cations,
for example if the element used as an activator is a
cation, the combination of cations should have an e.n. of
not more than 1.4, which in the description and claims is
defined to mean, the weighted average of the
electronegativities of the cations shall not be more than
1.4. In that case it is possible that a small part of the
cations in the luminescent material per se has for itself
an e.n. higher than 1.4.
Preference is given to low-pressure mercury vapour
discharge lamps according to the invention containing a
luminescent material which has the property that it
furnishes, after the above-described ultra-violet
irradiation for 15 minutes, a luminous flux which is not
more than 3% smaller than the initial luminous flux.
Luminescent materials which have such a low short term
decrease result in lamps having a very high luminous flux,
also with very high wall loads.
In lamps according to the invention an electric field
strength of 150 to 1000 V/m is preferably maintained in the
column discharge during operation. This relatively high
field strength can be obtained by using an envelope having
a relatively small diameter. With a relatively low lamp
current, compact, highly loaded lamps having a high
luminous flux are then obtained."